10/9/2021 News The Absolute Best Science Experiment for (1S,2S)-Cyclohexane-1,2-diamine

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.21436-03-3, Name is (1S,2S)-Cyclohexane-1,2-diamine, molecular formula is C6H14N2. In a Article,once mentioned of 21436-03-3, name: (1S,2S)-Cyclohexane-1,2-diamine

The synthesis and properties of four chiral, dinuclear, macrocyclic, cationic copper(II) complexes, [Cu2(Lm,n)]2+ (1-4), are described. The two symmetrical compounds [Cu2(L2,2)][ClO4]2 (1 and 2) were synthesized in a one-step reaction from 2,6-diformyl-4-tert.-butylphenol, copper(II)-perchlorate and the chiral diamine (1S,2S)-1,2-diphenylethylenediamine (synthesis of 1) and (1R,2R)-1,2-diaminocyclohexane (synthesis of 2), respectively. For the synthesis of the two unsymmetrical compounds [Cu2(LPh,n)]-[ClO4]2 (3 and 4) the mononuclear, neutral copper(II) complex [CuLPh] (5) [synthesized from 2,6-diformyl-4-tert.-butylphenol, copper(II)-acetate and 1,2-phenylenediamine] was reacted with (1R,2R)-1,2-diaminocyclohexane (synthesis of 3) and (S)-1,1?-binaphthyl-2,2?-diamine (synthesis of 4), respectively. The structures of the two unsymmetrical copper(-II) compounds (3 and 4) were determined by X-ray diffraction. WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2001.

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Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare