Synthetic Route of 1436-59-5, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 1436-59-5, C6H14N2. A document type is Article, introducing its new discovery.
Reaction of Co(CH3COO)2·4H2O, KTCNQ (TCNQ = 7,7,8,8-tetracyanoquinodimethane) with the racemic or chiral H 2salency (N,N?-bis(salicylidene)-1,2-cyclohexanediamine) ligand afforded three Co(iii) complexes K[Co(salency)(CN)2]·CH 3OH (1), K[Co(S,S-salency)(CN)2]·H2O (1S) and K[Co(R,R-salency)(CN)2]·CH3OH (1R), which have been fully characterized. The cyanide groups in these three complexes are generated from the in situ decomposition of the radical anion of TCNQ with the participation of cobalt(ii). Single-crystal X-ray diffraction analysis reveals that complex 1 exhibits an infinite double stair-like chain structure. However, the chiral complexes 1S and 1R show chain structures consisting of two independent sub-chains. All of these chains are bridged by the K+ ions, with the cyanides interacting with K+ in the end-on and unusual side-on pi-type mode. Second-order nonlinear optical effect studies in the solid state revealed that 1S and 1R are SHG active. The Royal Society of Chemistry.
If you are hungry for even more, make sure to check my other article about 1436-59-5. Synthetic Route of 1436-59-5