Application of 1436-59-5. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 1436-59-5, Name is cis-Cyclohexane-1,2-diamine. In a document type is Article, introducing its new discovery.
Copper(i) (±)-N,N?-bis(2,4,6-trimethylbenzylidene)-1,2- diaminocyclohexane reacts with either ethene or butadiene to give the corresponding alkene complexes. In each case crystallographic studies show that the alkene coordinates in an eta2 fashion. In the butadiene complex a dimer is formed where the butadiene bridges two copper complexes. Variable temperature NMR spectroscopy of the ethene adduct demonstrates fluxional behaviour, which is attributed to the rotation of the coordinated ethene relative to the complex, DeltaG?255 = 50 ± 2 kJ mol-1.
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