Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 2244-16-8, Name is (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone, molecular formula is , belongs to chiral-catalyst compound. In a document, author is Sadhukhan, Dipali, Safety of (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone.
Two chiral Schiff base ligands 2-((1-hydroxy-3-phenylpropan-2-ylimino)methyl)-6-methoxyphenol ((LH2)-H-1 ) and 2-(4-hydroxy-3-isopropylbut-1-enyl)-6-methoxyphenol ((LH2)-H-2 ) have been synthesized by the condensation of l-phenylalaninol/l-valinol and o-vanillin (2-hydroxy-3-methoxy benzaldehyde). A tetranuclear homometallic Cu(II) complex [Cu-4((LH)-H-1)(2)(L-1)(2)] (ClO4)(2) (C1) and a hexanuclear heterometallic complex [Cu-4(L-2)(4)Na-2(DMF)(2)(H2O)] (ClO4)(2) (C2) have been synthesized with the ligands. Both the complexes possess cubane like Cu4O4 core with interesting structural variations and inherit the chirality of their corresponding ligands. The catalytic potential of the complexes has been explored for the oxidative kinetic resolution of racemic benzoin. The electronic, optical and chiroptical properties of the ligands and the complexes have been studied by DFT and TD-DFT calculations.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 2244-16-8, in my other articles. Safety of (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare