In an article, author is Dong, Mengxian, once mentioned the application of 2244-16-8, Application In Synthesis of (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone, Name is (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone, molecular formula is C10H14O, molecular weight is 150.2176, MDL number is MFCD00062997, category is chiral-catalyst. Now introduce a scientific discovery about this category.
The mixtures of axially chiral (aR,S)- and (aS,S)-biscarboline alcohols were firstly used as catalysts in enantioselective 1,2- and 1,4-transfer hydrogenations of ketimines and beta-enamino esters, respectively. This mixed axially chiral catalysts exhibited excellent enantioselectivity (up to 98%ee) in the transfer hydrogenations under mild reaction conditions. (C) 2021 Elsevier Ltd. All rights reserved.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare