Chemistry is an experimental science, Quality Control of 2,2′-((Ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenol, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 94-93-9, Name is 2,2′-((Ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenol, molecular formula is C16H16N2O2, belongs to chiral-catalyst compound. In a document, author is Bertuzzi, Giulio.
A highly stereoselective 1,3-dipolar [6+4] cycloaddition towards bridged azabicyclo[4.3.1]decane scaffolds has been developed, reacting aldehydes, 2-aminomalonates and tropone under mild conditions in the presence of a chiral phosphoric acid catalyst. The scope is demonstrated for a series of aldehydes and 2-aminomalonates, and the reaction proceeds in high yields, >95:5 d.r. and up to 99 % ee. A series of transformations, as well as a mechanistic proposal, are presented.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 94-93-9. Quality Control of 2,2′-((Ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenol.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare