Reference of 1806-29-7. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1806-29-7, Name is 2,2-Biphenol
Photolysis of o-methylphenyl ketones generates o-quinodimethane intermediates that can be trapped in situ by dienophiles through Diels-Alder cycloadditions. This well-known photochemical process is applied to a series of six new photoreactive monomers containing bis(o-methylphenyl ketone) functionalities combined with diacrylate and triacrylate esters for the development of acrylic ester copolymer blends. Irradiation of cyclohexanone solutions of the bis(o-methylphenyl ketone)s and acrylate esters produce thin polymer films. Solid state 13C NMR data indicated 47-100% reaction of the bis(o-methylphenyl ketone)s, depending on experimental conditions, to yield the desired products. DSC and TGA analyses were performed to determine the glass transition temperature, Tg, and onset of decomposition, T d, of the resulting polymer films. A statistical “design of experiments” approach was used to obtain a systematic understanding of the effects of experimental variables on the extent of polymerization and the final polymer properties.
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Chiral Catalysts,
Chiral catalysts – SlideShare