Related Products of 14187-32-7. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 14187-32-7, Name is Dibenzo-18-crown-6
The spectrophotometric kinetic charge-transfer complex formation of iodine trichloride (ICl3) with Dibenzo-18-crown-6 (DB18C6), Dicyclohexyl-18-crown-6 (DC18C6) has been studied in chloroform; dichloromethane and propylene carbonate solutions at different temperatures. The results indicated immediate formation of an electron donor-electron acceptor complex; which is followed by two relatively slow consecutive reactions. The pseudo-first-order rate constants for the formation of the ionic intermediate and the final product have been evaluated at various temperatures by computer fitting of the absorbance-time data to appropriate equations. The influences of both the crown’s structure and the solvent properties on the formation of donor-electron acceptor complexes and the rates of subsequent reactions are discussed.
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