Reference of 14098-44-3, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.14098-44-3, Name is Benzo-15-crown-5, molecular formula is C14H20O5. In a patent, introducing its new discovery.
Reaction of Nicl2·6H2o and Na2[mnt] (mnt = maleonitriledithiolate) in Ch3oh at room temperature leads to Ni(ii) dithiolato complex [ni(mnt)2]2-. An oxidation process of [Ni(mnt)2]2- affords [{Ni(mnt)2}2]2- and yields solid crystalline product [Na2(benzo-15-Crown-5)3(H2O)2][{Ni(mnt)2}2] (1) in the presence of benzo-15-crown-5. X-ray diffraction analyses revealed that in solid state the dianions of 1 pack as columns and the counter ions are discrete disodium triple-decker dications. A non-linear absorption coefficient beta of 2.4 cm GW-1 was recorded at 1064 nm for 1 in acetonitrile solution with a concentration of 1.0 x 10-4 mol 1-1. (C) 2000 Elsevier Sciences S.A.
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