Application of 14187-32-7, An article , which mentions 14187-32-7, molecular formula is C20H24O6. The compound – Dibenzo-18-crown-6 played an important role in people’s production and life.
Raman and IR spectra of 18-crown-6 with cations were measured for their aqueous solutions and crystals.A Cs symmetry conformation of 18-crown-6 in its complexes with divalent cations was deduced, based on the solvent effect on the spectra of 18-crown-6 and also normal vibration calculation.Conformation analyses by spectral patterns revealed that the electric charge of captured cations determines the conformation of 18-crown-6 in complexes in solutions, while that of the crystals is affected by the ionic diameter of captured cations.
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