Discovery of Dibenzo-18-crown-6

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Synthetic Route of 14187-32-7, An article , which mentions 14187-32-7, molecular formula is C20H24O6. The compound – Dibenzo-18-crown-6 played an important role in people’s production and life.

The Zn(BH4)2 · 15-crown-5, Zn(BH4)2 · 18-crown-6, and Zn(BH4)2 · dibenzo-18-crown-6 complexes, which are insoluble in diethyl ether, were prepared by the reaction of zinc tetrahydroborate with oxygen-containing macrocyclic ligands in the ratio 1 : 1 in diethyl ether. The complexes were characterized by chemical analysis, IR spectroscopy, and differential thermal analysis.

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Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare