A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane, molecular formula is C10H20O5. In a Article£¬once mentioned of 33100-27-5, Safety of 1,4,7,10,13-Pentaoxacyclopentadecane
Microsolvation of K+/15-crown-5 in water, methanol and acetonitrile: An ab initio theoretical study with spectroscopic measurements on the acetonitrile solutions
An ab initio computational study of the formation of complexes of the potassium ion with the crown ether 15-crown-5 in three solvents, water, methanol and acetonitrile, is reported. The binding energy of the complexes has been analysed to identify contributions from structural changes and pair-wise interactions. The importance of the variation of the ion/solvent contribution to the binding energy in different solvents has been established. Reaction schemes have been investigated in which ion/solvent clusters interact with the crown ether to form complexes containing one crown ether molecule or sandwich complexes with two crown ether molecules. The relative importance of the two kinds of complex in the three solvents has been studied. New spectroscopic (IR and 13C NMR) data has been obtained on the acetonitrile solutions which can be interpreted within the general scheme of the theoretical calculations.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of 1,4,7,10,13-Pentaoxacyclopentadecane. In my other articles, you can also check out more blogs about 33100-27-5
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare