Extended knowledge of Benzo-15-crown-5

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Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 14098-44-3, C14H20O5. A document type is Conference Paper, introducing its new discovery., Safety of Benzo-15-crown-5

The thermodynamic functions of complex formation of benzo-15-crown-5 ether (B15C5) and sodium cation (Na+) in acetone-water mixtures at 298.15 K have been calculated. The equilibrium constants of B15C5/Na+ complex formation have been determined by conductivity measurements. The enthalpic effect of complex formation has been measured by the calorimetric method. The complexes are enthalpy-stabilized but entropy-destabilized in acetone-water mixtures. The effects of hydrophobic hydration, preferential solvation of B15C5 by a molecule of water and acetone, respectively and the solvation of Na + on the complex formation processes have been discussed. The calculated thermodynamic functions of B15C5/Na+ complex formation and the effect of benzene ring on the complex formation have been compared with analogous data obtained in dimethylsulfoxide-water mixtures. The effect of carbonyl atom replacement in acetone molecule by sulphur atom (DMSO molecule) on the thermodynamic functions of complex formation has been analysed. Akademiai Kiado, Budapest, Hungary 2009.

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Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare