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Cu-catalyzed arylation of phosphinic amide facilitated by (¡À)-trans-cyclohexane-1,2-diamine
Cu-catalyzed cross coupling between phosphinic amides and aryl halides was accomplished for the first time by using (¡À)-trans-cyclohexane-1,2-diamine as the ligand. This reaction provided a novel approach for synthesizing arylated phosphinic amides. Both kinetic measurement and theoretical calculation indicated that phosphinic amides were much less reactive than amides by about 10 times in Cu-catalyzed cross coupling.
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Chiral Catalysts,
Chiral catalysts – SlideShare