2244-16-8, Name is (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone, molecular formula is C10H14O, belongs to chiral-catalyst compound, is a common compound. In a patnet, author is Zou, Liangliang, once mentioned the new application about 2244-16-8, Name: (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone.
An efficient enantioselective synthesis of cyclic alpha-aminophosphonates via multicomponent reactions of 2-alkynylbenzaldehydes, amines, and dimethylphosphonate has been developed with the use of a chiral silver spirocyclic phosphate as the catalyst. This protocol provides straightforward access to a series of chiral C1-phosphonylated 1,2-dihydroisoquinoline derivatives with high yields (up to 99%) and high enantioselectivities (up to 94% ee) for a broad substrate scope. The products could be further transformed into densely functionalized compounds and corresponding alpha-aminophosphonic acids.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare