Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 1210348-34-7, Name is tert-Butyl ((1R,2S,5S)-2-amino-5-(dimethylcarbamoyl)cyclohexyl)carbamate oxalate, SMILES is O=C(OC(C)(C)C)N[C@H]1[C@@H](N)CC[C@H](C(N(C)C)=O)C1.O=C(O)C(O)=O, in an article , author is Wang, Cuiying, once mentioned of 1210348-34-7, Application In Synthesis of tert-Butyl ((1R,2S,5S)-2-amino-5-(dimethylcarbamoyl)cyclohexyl)carbamate oxalate.
An efficient C-P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)(2)/dppf as a catalyst, affording a series of (S) or (R)-Pchiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 1210348-34-7, you can contact me at any time and look forward to more communication. Application In Synthesis of tert-Butyl ((1R,2S,5S)-2-amino-5-(dimethylcarbamoyl)cyclohexyl)carbamate oxalate.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare