The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane, molecular formula is C10H20O5. In a Article£¬once mentioned of 33100-27-5, Recommanded Product: 33100-27-5
Transition-metal-free and halogen-free controlled synthesis of poly(3-alkylthienylene vinylene): Via the Horner-Wadsworth-Emmons condensation reaction
Transition metal catalysts and halogens are necessary for the controlled synthesis of pi-conjugated polymers; the contamination by transition-metal-based and halogen-based byproducts generally adversely affects the performance of organic devices. In this study, we demonstrate a transition-metal-free and halogen-free controlled synthesis of poly(3-alkylthienylene vinylene) (P3ATV) via Horner-Wadsworth-Emmons polycondensation. The electrophilicity of the formyl group in the AB-type monomer, (3-(2-ethylhexyl)-5-formyl-thiophene-2-ylmethyl)phosphonic acid diethyl ester, could be deactivated by resonance effect using the appropriate base (NaHMDS/15-crown-5-ether). The initiator, 5-nitro-2-thiophenecarboxaldehyde, which contains the active formyl group, readily initiated the polymerization to afford well-defined P3ATV in a chain-growth manner. The molecular weights of the polymers were controlled (1800-10-200) by the feeding monomer/initiator ratio while maintaining narrow molecular weight distributions (1.20-1.28). Furthermore, the chain extension by post-polymerization could proceed effectively, highlighting the quasi-living nature of the proposed method.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 33100-27-5 is helpful to your research., Recommanded Product: 33100-27-5
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare