In an article, published in an article, once mentioned the application of 21436-03-3, Name is (1S,2S)-Cyclohexane-1,2-diamine,molecular formula is C6H14N2, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of (1S,2S)-Cyclohexane-1,2-diamine
Modular multidentate phosphine ligands: Application to palladium-catalyzed allylic alkylations
Multidentate phosphines were readily obtained by reaction of chiral multidentate amines, prepared via ring opening of (S)-N-tosyl-2- isopropylaziridine with ammonia, primary, and secondary amines, with achiral phosphorus containing building blocks. The phosphines were used in palladium-catalyzed alkylation of rac-3-cyclohexenyl and cyclopentenyl carbonates. The enantioselectivity and reactivity were largely dependent on the structure of the amine core of the ligands. Up to 88% ee was observed in reactions with the six-membered substrate. The Royal Society of Chemistry 2006.
Do you like my blog? If you like, you can also browse other articles about this kind. Application In Synthesis of (1S,2S)-Cyclohexane-1,2-diamine. Thanks for taking the time to read the blog about 21436-03-3
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare