14098-44-3, Name is Benzo-15-crown-5, molecular formula is C14H20O5, belongs to chiral-catalyst compound, is a common compound. In a patnet, once mentioned the new application about 14098-44-3, name: Benzo-15-crown-5
Synthesis, crystal structure and electrochemical properties of a new adduct of Benzo-15-crown-5 and H3PMo12O40
A new crown ether-POM (POM = polyoxometalate) adduct with the molecular formula [(C14-H20O5)4(H 3O)3]PMo12O40 ¡¤0.5CH 3CN (1) was isolated from the mixed solvent of acetonitrile and methanol. The adduct is constructed from Keggin [PMo12O 40]3- anions and [(C14H20O 5)-(H3O+)] and [(C14H 20O5)2(H3O+)] cations via electrostatic and hydrogen bonding interactions. The supramolecular interactions combine the crown ether with oxonium ions. In the [(C 14H20O5)-(H3O+)] moieties, the oxonium ions reside out of the planes defined by the oxygen atoms of the crown ether. The [(C14H20O5) 2(H3O+)] moieties exhibit a sandwich structure. There exist hydrogen bonds between the oxonium ions of the [(C 14H20O5)(H3O)]+ cations and the acetonitrile molecules and the terminal and bridging oxygen atoms of the [PMo12O40]3- anions. The adduct has been used as a bulk-modifier to fabricate a chemically modified carbon paste electrode (MCPE), which displays well-defined cyclic voltammograms with three reversible two-electron redox couples in acidic aqueous solution, and electrocatalytic activities towards the reduction of H2O2 and NO 2-.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Benzo-15-crown-5. In my other articles, you can also check out more blogs about 14098-44-3
Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare